能源化学(英文)
ISSN 1003-9953
     
天然气化学(英文) 2011, Vol. 20 Issue (3) :318-324    DOI: 10.1016/S1003-9953(10)60187-9
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Methanation of carbon dioxide on Ni/ZrO2-Al2O3 catalysts: Effects of ZrO2 promoter and preparation method of novel ZrO2-Al2O3 carrier
Mengdie Cai1, Jie Wen1*, Wei Chu1, Xueqing Cheng2, Zejun Li2

1. Department of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China; 2. Southwest Research & Design Institute of Chemical Industry,

Chengdu 610000, Sichuan, China

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摘要 The novel nickel-based catalysts with a nickel content of 12 wt% were prepared with the zirconia-alumina composite as the supports. The new carriers, ZrO2 improved alumina, were synthesized by three methods, i.e., impregnation-precipitation, co-precipitation, and impregnation method. The catalytic properties of these catalysts were investigated in the methanation of carbon dioxide, and the samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), temperature-programmed reduction (TPR) and temperature-programmed desorption (TPD) techniques. The new catalysts showed higher catalytical activity and better stability than Ni/γ-Al2O3. Furthermore, as a support for new nickel catalyst, the ZrO2-Al2O3 composite prepared by the impregnation-precipitation method was more efficient than the other supports in the methanation of carbon dioxide. The highly dispersed zirconium oxide on the surface of γ-Al2O3 inhibited the formation of nickel aluminate-like phase, which was responsible for the better dispersion of Ni species and easier reduction of NiO species, leading to the enhanced catalytic performance of corresponding catalyst.
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作者相关文章
Mengdie Cai
Jie Wen*
Wei Chu
Xueqing Cheng
Zejun Li
关键词zirconia-alumina composite   nickel catalyst   CO2   methanation   preparation method     
收稿日期: 2010-12-30; 发布日期: 2011-05-20
基金资助:

国家重点基础研究发展计划

通讯作者 储伟     Email: chuwei65@yahoo.com.cn
引用本文:   
Mengdie Cai, Jie Wen*, Wei Chu等 .Methanation of carbon dioxide on Ni/ZrO2-Al2O3 catalysts: Effects of ZrO2 promoter and preparation method of novel ZrO2-Al2O3 carrier[J]  天然气化学(英文), 2011,V20(3): 318-324
Mengdie Cai, Jie Wen*, Wei Chu etc .Methanation of carbon dioxide on Ni/ZrO2-Al2O3 catalysts: Effects of ZrO2 promoter and preparation method of novel ZrO2-Al2O3 carrier[J]  Journal of Natural Gas Chemistry, 2011,V20(3): 318-324
链接本文:  
http://www.jngc.org/CN/10.1016/S1003-9953(10)60187-9     或     http://www.jngc.org/CN/Y2011/V20/I3/318
 
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