能源化学(英文)
ISSN 1003-9953
     
天然气化学 2012, Vol. 21 Issue (1) :49-55    DOI: 10.1016/S1003-9953(11)60332-0
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Oxidative coupling of methane over BaCl2-TiO2-SnO2 catalyst
 Zhonglai Wang1,2, Guojun Zou1, Xu Luo1,2, Hua Liu2, Runxiong Gao1, Lingjun Chou1*, Xiaolai Wang1*

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000,

Gansu, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 10039, China  

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摘要 The performance of BaCl2-TiO2-SnO2 composite catalysts in oxidative coupling of methane reaction has been investigated. A series of BaCl2-TiO2, BaCl2-SnO2, TiO2-SnO2, and BaCl2-TiO2-SnO2 catalysts were prepared, and characterized by BET, XRD, XPS, CO2-TPD and H2-TPR, respectively. The synergistic effect among BaCl2, SnO2 and TiO2 compositions enhances the catalytic performance. The best C2 selectivity and ethylene yield are obtained on the catalyst with the equal molar amount of the three compositions (BaCl2 : TiO2 : SnO2 molar ratio of 1 : 1 : 1). The optimal reaction condition is as follows: 800 ℃, 44 mL·min-1 for methane, 22 mL·min-1 for oxygen and a space velocity of 5000 mL·h-1·g-1. And the C2H4 yield over the catalyst is 20.1% with the CH4 conversion of 43.8% and C2 selectivity of 53.3%.
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Zhonglai Wang
Guojun Zou
Xu Luo
Hua Liu
Runxiong Gao
Lingjun Chou*
Xiaolai Wang*
关键词oxidative coupling of methane   BaCl2-TiO2-SnO2 catalyst   synergistic effect   Na2WO4-Mn/SiO2 catalyst      
收稿日期: 2011-05-31; 发布日期: 2012-01-12
通讯作者 丑凌军     Email: ljchou@licp.cas.cn
引用本文:   
Zhonglai Wang, Guojun Zou, Xu Luo等 .Oxidative coupling of methane over BaCl2-TiO2-SnO2 catalyst[J]  天然气化学 , 2012,V21(1): 49-55
Zhonglai Wang, Guojun Zou, Xu Luo etc .Oxidative coupling of methane over BaCl2-TiO2-SnO2 catalyst[J]  Journal of Energy Chemistry, 2012,V21(1): 49-55
链接本文:  
http://www.jenergchem.org/CN/10.1016/S1003-9953(11)60332-0     或     http://www.jenergchem.org/CN/Y2012/V21/I1/49
 
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