? 能源化学(英文)
ISSN 1003-9953
     
能源化学(英文) 2017, Vol. 26 Issue (1) :147-154    DOI: 10.1016/j.jechem.2016.09.010
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Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural
Jiawei Zhonga,b, Yuanyuan Guoa, Jinzhu Chena
a Key Laboratory of Renewable Energy, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
b University of Chinese Academy of Sciences, Beijing 100049, China
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摘要 A serial of protonated and layered transition metal oxides, including layered HTaWO6, HNbMoO6 as well as HNbWO6, were synthesized by solid-state reaction and ion-exchange. The layered HTaWO6 has been systematically studied as a solid acid to realize the dehydration of fructose to 5-hydroxymethylfurfural (HMF). The transition metal oxide samples were characterized with ICP-OES, EDS, XRD, XPS, SEM, TGA, FT-IR, N2 adsorption-desorption and NH3-TPD. The influential factors such as reaction temperature, reaction time, solvent, catalyst amount and substrate concentration were deeply investigated. The optimized fructose conversion rate of 99% with HMF yield of 67% were achieved after 30 min at 140℃ in dimethylsulfoxide.
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关键词Biomass   Dehydration   5-Hydroxymethylfurfural   Layered transition metal oxide   Solid acid     
收稿日期: 2016-05-17; 发布日期: 2016-10-03
基金资助:

This work was supported by the National Natural Science Foundation of China (21472189), National Basic Research Program of China (973 Program, 2012CB215304), the Natural Science Foundation of Guangdong Province, China (2015A030312007), Guangdong Key Laboratory of New and Renewable Energy Research and Development (Y607jl1001) and Science and Technology Planning Project of Guangdong Province, China (2015A010106010).

通讯作者 Jinzhu Chen     Email: chenjz@ms.giec.ac.cn
引用本文:   
.Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural[J]  能源化学(英文) , 2017,V26(1): 147-154
.Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural[J]  Journal of Energy Chemistry, 2017,V26(1): 147-154
链接本文:  
http://www.jenergchem.org/CN/10.1016/j.jechem.2016.09.010     或     http://www.jenergchem.org/CN/Y2017/V26/I1/147
 
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