能源化学(英文)
ISSN 1003-9953
     
能源化学(英文) 2017, Vol. 26 Issue (1) :193-199    DOI: 10.1016/j.jechem.2016.11.014
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Highly efficient and stable electrooxidation of methanol and ethanol on 3D Pt catalyst by thermal decomposition of In2O3 nanoshells
Yuhang Xiea, Hulin Zhanga,b, Guang Yaoa, Saeed Ahmed Khana, Xiaojing Cuic, Min Gaoa,b, Yuan Lina,b
a State Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China;
b Center for Information in Medicine, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China;
c The First Sub-Institute, Nuclear Power Institute of China, Chengdu 610041, Sichuan, China
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摘要 In this paper In2O3 nanoshells have been synthesized via a facile hydrothermal approach. The nanoshells can be completely cracked into pony-size nanocubes by annealing, which are then used as a support of Pt catalyst for methanol and ethanol electrocatalytic oxidation. The prepared In2O3 and supportedPt catalysts (Pt/In2O3) were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field effect scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry and electrochemical impedance spectroscopy (EIS) were carried out, indicating the excellent catalytic performance for alcohol electrooxidation can be achieved on Pt/In2O3 nanocatalysts due to the multiple active sites, high conductivity and a mass of microchannels and micropores for reactant diffusions arising from 3D frame structures compared with that on the Pt/C catalysts.
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关键词In2O3   Pt catalyst   Electrocatalytic oxidation   Alcohol     
收稿日期: 2016-07-18; 发布日期: 2016-11-22
基金资助:

This work is sponsored by the National Basic Research Program of China (973 Program) under grant no. 2015CB351905, the National Natural Science Foundation of China (no. 61504019), China Postdoctoral Science Foundation (no. 2015M580783), Scientific Research Start-up Foundation of University of Electronic Science and Technology of China (Y02002010301082), the Technology Innovative Research Team of Sichuan Province of China (no. 2015TD0005), and the Fundamental Research Funds for the Central Universities of China (no. ZYGX2015J140).

通讯作者 Hulin Zhang, Yuan Lin     Email: zhangd198710@gmail.com;linyuan@uestc.edu.cn
引用本文:   
.Highly efficient and stable electrooxidation of methanol and ethanol on 3D Pt catalyst by thermal decomposition of In2O3 nanoshells[J]  能源化学(英文) , 2017,V26(1): 193-199
.Highly efficient and stable electrooxidation of methanol and ethanol on 3D Pt catalyst by thermal decomposition of In2O3 nanoshells[J]  Journal of Energy Chemistry, 2017,V26(1): 193-199
链接本文:  
http://www.jenergchem.org/CN/10.1016/j.jechem.2016.11.014     或     http://www.jenergchem.org/CN/Y2017/V26/I1/193
 
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